Chemistry Solids UHS 2023
PMDC Verified Question 19 of 54
In metals, why electric conductivity decreases with the increases of temperature?
A
Because electron movement decrease with the increase of temperature
B
Because metal ions oscillations hinder electron movement
C
Because electron direction changes at high temperature
D
Because they pass heat current through collision of electrons
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Because metal ions oscillations hinder electron movement
Concept:
Metallic conduction relies on the free flow of a "sea of electrons" past positively charged metal kernels (ions) situated at the lattice points.

Solution:
  • As the temperature of a metal increases, the thermal energy is converted into kinetic energy.
  • This causes the positive metal ions at the lattice points to oscillate/vibrate much more vigorously around their mean positions.
  • These intense oscillations increase the frequency of collisions between the flowing free electrons and the vibrating metal ions.
  • This scattering essentially "hinders" the electron movement, increasing resistance and thus decreasing electric conductivity.


Why other options are incorrect:
  • A: The kinetic energy and movement of the electrons themselves actually increase with temperature, they just face more obstacles.
  • C, D: These do not accurately describe the mechanism of electrical resistance in metallic lattices.

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