Chemistry Solids NUMS 2023
PMDC Verified Question 30 of 54
Thermal conductivity of metals is due to:
A
Layered structure of metals
B
Freely moving electrons
C
Loosely hold metal atoms
D
Vibrational movement of metals
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Freely moving electrons
Concept:
Metals are excellent conductors of both heat and electricity due to their unique atomic structure, specifically the "electron sea" model.

Solution:
  • In a metallic lattice, the valence electrons detach from individual atoms and become delocalized, forming a "sea" of freely moving electrons.
  • When heat is applied to one end of a metal, these highly mobile free electrons gain kinetic energy.
  • Because they can move freely and rapidly throughout the entire crystal lattice, they quickly transfer this thermal energy to cooler regions via collisions.
  • Therefore, the high thermal conductivity of metals is primarily due to freely moving electrons.


Why other options are incorrect:
  • D: While vibrational movement of atoms (phonons) does contribute slightly to thermal conductivity, the overwhelmingly dominant mechanism in metals is electron transport.
  • A, C: Metals do not generally have "layered structures" (unlike graphite), and their atoms are tightly packed, not "loosely held".

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