Chemistry Stoichiometry MDCAT 2019
PMDC Verified Question 82 of 105
During stoichiometric calculations, which of the following laws must be followed?
A
Law of conservation of mass
B
Law of conservation of energy
C
Avogadro’s law
D
Dalton’s law
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Law of conservation of mass
Concept:

Stoichiometry is fundamentally built upon the premise that atoms are never created or destroyed in chemical reactions. They merely rearrange. Thus, the total mass before and after a reaction must be identical.

Formula:

$$ \text{Mass of Reactants} = \text{Mass of Products} $$

Solution:

  • The Law of Conservation of Mass states that matter can neither be created nor destroyed.


  • When we balance a chemical equation for stoichiometric calculations, we are physically ensuring that the number of atoms for every element is identical on both sides.


  • This direct balancing act is the practical application of the Law of Conservation of Mass (alongside the Law of Definite Proportions).


Why other options are incorrect:

  • Law of conservation of energy: While true in physics, it is not the basis for balancing atoms in reaction stoichiometry.


  • Avogadro’s law: Applies specifically to volumes of gases, not generalized stoichiometry involving solids and liquids.


  • Dalton’s law: Pertains to partial pressures of non-reacting gas mixtures, entirely unrelated to mass balancing.

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