Chemistry Stoichiometry NUMS 2022
PMDC Verified Question 61 of 105
The 1st step involved in the determination of Empirical formula of chemical compound is:
A
Finding number of gram atoms of each element
B
Percentage composition of each element
C
Atomic ratio of each element
D
Multiplication of atomic ratio with whole number
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Percentage composition of each element
Concept:

Calculating an empirical formula requires a rigid step-by-step analytical process, beginning with identifying how much of the compound is made of each element by mass.

Formula:

$$ \text{Step 1: } \% \text{ Composition} \rightarrow \text{Step 2: Moles} \rightarrow \text{Step 3: Ratio} $$

Solution:

  • Step 1: Determine the percentage composition by mass of each constituent element (often via combustion analysis).


  • Step 2: Convert those percentages into moles (gram atoms) by dividing by the respective atomic masses.


  • Step 3: Determine the atomic ratio by dividing all mole values by the smallest mole value found.


  • Step 4: If the ratio contains fractions, multiply by a whole number to achieve integer subscripts.


Why other options are incorrect:

  • Options A, C, and D: These are the second, third, and fourth steps respectively. You cannot find gram atoms (moles) without first knowing the mass percentage (Step 1).

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