Chemistry Thermochemistry MDCAT 2018
PMDC Verified Question 65 of 81
Reaction of water with quick lime result in the rise in the temperature of the system. Using the temperature change, indicate the nature of the reaction?
A
Third order reaction
B
Exothermic reaction
C
Non spontaneous reaction
D
Endothermic reaction
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Exothermic reaction
Concept:

When a chemical reaction releases heat energy, that energy is transferred to the immediate surroundings (the system's medium), resulting in an observable rise in temperature.

Formula:

$$ CaO_{(s)} + H_2O_{(l)} \rightarrow Ca(OH)_{2(aq)} \quad \Delta H = -\text{ve} $$

Solution:

  • Quick lime (\( CaO \)) reacts vigorously with water to form slaked lime (\( Ca(OH)_2 \)).


  • The question states there is a "rise in the temperature of the system", which is the hallmark macroscopic observation of heat being evolved.


  • Reactions that evolve heat are exothermic (\( \Delta H < 0 \)).


Why other options are incorrect:

Endothermic reactions absorb heat and cause a drop in temperature. Reaction order (Third order) describes kinetics, not thermodynamics. The reaction is highly spontaneous, ruling out non-spontaneous.

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