Chemistry Thermochemistry MDCAT 2017
PMDC Verified Question 68 of 81
Enthalpy is measured at:
A
298 K and 1 atm
B
300 K and 1 atm
C
300 K and 2 atm
D
295 K and 1 atm
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: 298 K and 1 atm
Concept:

To compare enthalpy changes across different reactions universally, scientists define "standard conditions". When properties are measured under these conditions, they are referred to as standard enthalpy changes (\( \Delta H^\circ \)).

Formula:

$$ \text{Standard Temperature} = 25^\circ \text{C} = 298 \text{ K} $$
$$ \text{Standard Pressure} = 1 \text{ atm} $$

Solution:

  • In chemical thermodynamics, standard conditions specify that the pressure must be 1 atmosphere (or 100 kPa in modern IUPAC definitions, but historically 1 atm).


  • The designated standard temperature is strictly \( 25^\circ \text{C} \), which converts to 298 K.


  • Thus, standard enthalpy is measured at 298 K and 1 atm.


Why other options are incorrect:

300 K (\( 27^\circ \text{C} \)) and 295 K (\( 22^\circ \text{C} \)) are not accepted IUPAC standard thermodynamic temperatures. 2 atm is non-standard pressure.

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