Chemistry Thermochemistry MDCAT 2019
PMDC Verified Question 59 of 81
Which enthalpy change is relevant in the following process?
\( Na_{(s)} \rightarrow Na_{(g)} \quad \Delta H = +108 \text{ kJmol}^{-1} \)
A
Enthalpy of fusion
B
Enthalpy of formation
C
Enthalpy of vaporization
D
Enthalpy of atomization
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: Enthalpy of atomization
Concept:

Identifying the correct thermodynamic term requires matching the physical states and stoichiometry of the provided reaction equation to established definitions.

Formula:

$$ \text{Element (standard state)} \rightarrow 1 \text{ mole Gaseous Atoms} $$

Solution:

  • The equation shows solid sodium (\( Na_{(s)} \)), which is its standard state, transforming directly into isolated gaseous sodium atoms (\( Na_{(g)} \)).


  • Exactly 1 mole of gaseous atoms is produced.


  • This precise transformation is the definition of the Enthalpy of atomization (\( \Delta H_{at}^\circ \)). Note: For a monoatomic solid like Na, atomization is numerically equal to the enthalpy of sublimation.


Why other options are incorrect:

Enthalpy of fusion refers to Solid \( \rightarrow \) Liquid. Enthalpy of vaporization refers to Liquid \( \rightarrow \) Gas. Neither applies because this equation skips the liquid phase and starts from a solid to form gaseous atoms.

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