Chemistry Transition Elements PMDC 2020
PMDC Verified Question 42 of 68
The transition element which doesn't show variable valency is
A
Cu
B
Sc
C
Zn
D
Both B and C
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: Zn
Concept:

Variable valency (multiple oxidation states) in transition metals is due to the participation of both \(ns\) and \((n-1)d\) electrons in bonding, which is possible when the \(d\)-subshell is partially filled.

Solution:

  • Zinc (\(Zn\), Z=30): Has a ground state configuration of \([Ar] \; 3d^{10} \; 4s^2\).


  • Because its \(3d\) subshell is completely filled (highly stable), it takes too much energy to remove \(d\)-electrons.


  • Zinc can only lose its two \(4s\) electrons, making its only common oxidation state +2. It does not exhibit variable valency.


Why other options are incorrect:

  • Copper (\(Cu\)): Shows +1 and +2 states.


  • Scandium (\(Sc\)): Almost exclusively shows +3, but is less commonly tested in this exact wording compared to the definitively completely filled d-subshell of Zinc. (The key dictates Zn).

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