Chemistry Transition Elements UHS 2024
PMDC Verified Question 2 of 68
Electronic configuration of chromium (proton number 24) is:
A
\( [Ar], 3d^{4}, 4s^{2} \)
B
\( [Ar], 3d^{5}, 4s^{1} \)
C
\( [Ar], 3d^{5}, 4s^{2} \)
D
\( [Ar], 3d^{6}, 4s^{2} \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: \( [Ar], 3d^{5}, 4s^{1} \)
Concept:

Chromium is a classic exception to standard Aufbau filling rules. It adopts a configuration that maximizes thermodynamic stability.

Solution:

  • Chromium (\(Z=24\)) has an Argon core (18 electrons), leaving 6 valence electrons to place.


  • Standard filling predicts \(4s^2 \; 3d^4\).


  • However, moving one electron from the \(4s\) orbital into the \(3d\) orbital creates a \(3d^5\) state.


  • A \(3d^5\) configuration means the \(d\)-subshell is exactly half-filled, making it perfectly symmetrical. This symmetry minimizes electrostatic repulsion and maximizes exchange energy, rendering it highly stable.


  • Therefore, the correct configuration is \([Ar] \; 3d^5 \; 4s^1\).


Why other options are incorrect:

  • Option A: The expected but incorrect configuration.


  • Option C/D: These correspond to Manganese (\(Z=25\)) and Iron (\(Z=26\)) respectively.

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