Physics Electronics PMDC Conceptual Practice
PMDC Verified Question 214 of 494
Doping a pure Germanium crystal with a small concentration of trivalent Gallium (Ga) atoms produces which type of extrinsic semiconductor?
A
N-type semiconductor with excess free electrons
B
P-type semiconductor with excess valence holes
C
Intrinsic semiconductor with equal carrier densities
D
Insulating ceramic dielectric
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: P-type semiconductor with excess valence holes
Concept:

Trivalent impurity atoms (Group III, such as B, Al, Ga, In) have three valence electrons and create electron vacancies (holes) when substituting into a tetravalent semiconductor lattice, forming a P-type semiconductor.

Formula:

$$\text{Group III Dopant (Ga)} + \text{Group IV Host (Ge)} \implies \text{P-type Semiconductor } (p \approx N_A \gg n)$$

Solution:

  • Gallium has 3 valence electrons and bonds with 4 neighboring Germanium atoms, leaving one covalent bond incomplete.


  • This creates a vacancy (hole) in the valence band that can accept an electron, making holes the majority carriers in a P-type material.


Why other options are incorrect:

  • Option A: N-type semiconductors are formed using pentavalent (Group V) dopants.
  • Option C: Doping creates an extrinsic semiconductor, not an intrinsic one.
  • Option D: Doping increases semiconductor conductivity rather than forming an insulator.

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