Concept:Because higher temperatures break covalent bonds and exponentially increase free carrier concentration, semiconductor resistivity decreases with temperature, giving a negative temperature coefficient (\( \alpha < 0 \)).
Formula:$$\rho(T) = \rho_0 \exp\left(\frac{E_g}{2 k T}\right) \implies \alpha = \frac{1}{\rho} \frac{d\rho}{dT} = -\frac{E_g}{2 k T^2} < 0$$
Solution:- In metallic conductors, increased temperature causes lattice vibrations that increase resistance (\( \alpha > 0 \)).
- In semiconductors, thermal generation of new electron-hole pairs outweighs scattering effects, lowering resistance (\( \alpha < 0 \)).
Why other options are incorrect:- Option B: A positive temperature coefficient (\( \alpha > 0 \)) is characteristic of metallic conductors.
- Option C: Zero temperature coefficient is approximated by specialized precision alloys like Manganin.
- Option D: Semiconductor resistivity is finite at room temperature.
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