Chemistry Aldehydes & Ketones UHS 2024
PMDC Verified Question 3 of 94
Reaction of \( HCN \) with formaldehyde is a:
A
Nucleophilic addition reaction
B
Electrophilic addition reaction
C
Nucleophilic substitution reaction
D
Electrophilic substitution reaction
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: Nucleophilic addition reaction
Concept:

The mechanism of a reaction is defined by the first attacking species and the final connectivity of the product.

Solution:

  • Formaldehyde (\( HCHO \)) has a highly polarized \( C=O \) bond, making the carbon electrophilic (electron deficient).


  • The reaction with \( HCN \) requires a base catalyst to generate the Cyanide nucleophile (\( CN^- \)).


  • This nucleophile attacks the carbonyl carbon, breaking the \( \pi \) bond without kicking out any leaving groups.


  • Because an electron-rich species initiates the attack and the whole molecule adds across the double bond, it is a Nucleophilic addition reaction.


Why other options are incorrect:

Electrophilic additions are typical for \( C=C \) bonds. Substitutions require a leaving group to be displaced, which does not occur during cyanohydrin formation.

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