Chemistry Electrochemistry ETEA 2016
PMDC Verified Question 65 of 73
In which of the following reaction hydrogen acts as oxidizing agent.
A
\( H_2 + Cl_2 \rightarrow 2HCl \)
B
\( C_2H_4 + H_2 \rightarrow C_2H_6 \)
C
\( 2Na + H_2 \rightarrow 2NaH \)
D
\( N_2 + 3H_2 \rightarrow 2NH_3 \)
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: \( 2Na + H_2 \rightarrow 2NaH \)
Concept:

An oxidizing agent removes electrons from another substance, meaning the oxidizing agent itself gets reduced (its oxidation state decreases).

Solution:

  • We must find the reaction where Hydrogen's oxidation state decreases from \( 0 \) to a negative value.


  • In option C: \( 2Na + H_2 \rightarrow 2NaH \).


  • Sodium is a highly electropositive Group 1 metal (it desperately wants to lose an electron).


  • Elemental Hydrogen (\( 0 \)) is forced to accept an electron from Sodium, becoming the hydride ion (\( H^- \)) with an oxidation state of \( -1 \).


  • Because Hydrogen gains electrons and is reduced, it acts as the oxidizing agent.


Why other options are incorrect:

In reactions with more electronegative non-metals like Chlorine or Nitrogen, Hydrogen acts as the reducing agent, losing electron density and taking on a \( +1 \) oxidation state.

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