PMDC Verified Question 61 of 83
IUPAC name of Divinyl acetylene is:
A
1,5-hexadiene-3-ene
B
1,5-hexadiene-3-yne
C
3-Hexane-1,5-diyne
D
3-Hexyne-1,5-diene
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: 1,5-hexadiene-3-yne
Concept:

To determine the IUPAC name from a common name, deduce the structure first. The "vinyl" group is \( \text{-CH}=\text{CH}_2 \). Acetylene is \( \text{HC}\equiv\text{CH} \).

Solution:

  • Structure: Divinyl acetylene means two vinyl groups attached to an acetylene core: \( \text{CH}_2=\text{CH--C}\equiv\text{C--CH}=\text{CH}_2 \).


  • Chain length: The longest continuous chain has 6 carbons (hexa).


  • Numbering: Numbering from either side gives the double bonds at C1 and C5, and the triple bond at C3.


  • Suffixes: According to IUPAC, "ene" comes before "yne". The main chain is a 1,5-diene, and a 3-yne.


  • Combining them: hexa-1,5-dien-3-yne (or 1,5-hexadiene-3-yne).


Why other options are incorrect:

Option A incorrectly uses "ene" twice. Option C misidentifies the molecule as having two triple bonds (diyne). Option D improperly places "hexyne" before "diene" violating standard IUPAC assembly order.

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