PMDC Verified Question 62 of 83
Diethyl ether and n-butanol are:
A
Position isomerism
B
Functional isomerism
C
Chain isomerism
D
Tautomerism
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Functional isomerism
Concept:

Compounds that share the same molecular formula but have completely different functional groups exhibit functional group isomerism.

Solution:

  • Diethyl ether: \( \text{CH}_3\text{CH}_2\text{--O--CH}_2\text{CH}_3 \) (Functional group: Ether). Molecular formula: \( \text{C}_4\text{H}_{10}\text{O} \).


  • n-butanol: \( \text{CH}_3\text{CH}_2\text{CH}_2\text{CH}_2\text{OH} \) (Functional group: Alcohol). Molecular formula: \( \text{C}_4\text{H}_{10}\text{O} \).


  • Because they have identical formulas but different functional groups (ether vs. alcohol), they are functional isomers.


Why other options are incorrect:

Chain isomers differ in skeleton, position isomers differ in location of the same functional group, and tautomers are dynamic equilibrium isomers.

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