Chemistry Gases NUMS 2023
PMDC Verified Question 31 of 65
If both temperature and volume of gas are doubled, the pressure:
A
Cannot be predicted
B
Is reduced to 1/2
C
Remains unchanged
D
Is doubled
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: Remains unchanged
Concept:

To determine how pressure responds to simultaneous changes in both temperature and volume, we use the combined gas law.

Formula:

$$ P = \frac{nRT}{V} \quad \text{or} \quad \frac{P_1 V_1}{T_1} = \frac{P_2 V_2}{T_2} $$

Solution:

  • Let initial state be: Pressure = \( P \), Volume = \( V \), Temperature = \( T \). (Assuming moles, n, is constant).


  • The temperature is doubled: New Temperature = \( 2T \).


  • The volume is doubled: New Volume = \( 2V \).


  • Plug these into the ideal gas rearranged for new pressure \( (P_{new}) \):


  • \( P_{new} = \frac{nR(2T)}{(2V)} \).


  • The '2' in the numerator and the '2' in the denominator cancel each other out completely.


  • \( P_{new} = \frac{nRT}{V} = P_{original} \).


  • Therefore, the pressure remains exactly unchanged. The expansion of volume perfectly negates the increase in kinetic energy from the temperature.


Why other options are incorrect:

  • Options A, B, & D: Mathematical derivation proves the effects precisely cancel out, leaving no net change.

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