Chemistry Hydrocarbons MDCAT 2012
PMDC Verified Question 59 of 65
The introduction of R - C(=O) group in benzene is called
A
Alkylation
B
Carbonyl reduction
C
Acylation
D
Formylation
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: Acylation
Concept:

Reactions introducing specific functional groups onto an aromatic ring are named based on the functional group being attached.

Solution:

  • The \( \text{R}-\text{C}(=\text{O})- \) group is generally known as an acyl group.


  • Attaching this group to a benzene ring (typically via a Friedel-Crafts reaction with an acyl halide and \( \text{AlCl}_3 \)) is therefore formally termed acylation.


Why other options are incorrect:

  • Alkylation introduces a simple alkyl group (\( \text{R}- \)), not an acyl group.


  • Carbonyl reduction is the process of removing oxygen/adding hydrogen to a carbonyl group (e.g., Clemmensen reduction).


  • Formylation strictly refers to adding a formyl group (\( \text{H}-\text{C}(=\text{O})- \)), which is a specific, narrower subset of acylation.

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