Chemistry Industrial Chemistry PMDC Conceptual Practice
PMDC Verified Question 24 of 41
During an addition polymerization reaction, what occurs regarding the atomic composition of the reacting monomer units?
A
A fraction of the carbon skeleton is oxidized to carbon dioxide gas.
B
Hydrogen atoms are eliminated to produce conjugated polyene chains.
C
A small byproduct molecule such as water or alcohol is released.
D
All atoms of the original monomer are fully incorporated into the polymer backbone.
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option D: All atoms of the original monomer are fully incorporated into the polymer backbone.
Concept:

Addition polymerization proceeds with 100% atom economy; the molecular formula of the polymer repeating unit is identical to that of the monomer.

Formula / Reaction:

$$M_{\text{repeating unit}} = M_{\text{monomer}}$$

$$\text{Molecular Weight of Polymer } = n \times M_{\text{monomer}}$$

Solution:

  • The reaction involves rearrangement of \(\pi\)-bonding electrons into \(\sigma\)-bonds connecting adjacent monomers without the loss of any constituent atoms.


Why other options are incorrect:

  • Options A and B: No oxidation to \(\text{CO}_2\) or dehydrogenation occurs in standard addition polymerizations.


  • Option C: Elimination of small molecules characterizes condensation polymerization.

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