Chemistry Industrial Chemistry PMDC Conceptual Practice
PMDC Verified Question 25 of 41
What is the key functional group requirement for monomers participating in step-growth condensation polymerization?
A
A single reactive terminal functional site per monomer molecule
B
A completely non-polar, unreactive aliphatic hydrocarbon framework
C
At least two reactive functional groups (e.g., -OH, -COOH, -NH₂) per monomer molecule
D
An unsaturated carbon-carbon double bond with electron-donating alkyl substituents
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: At least two reactive functional groups (e.g., -OH, -COOH, -NH₂) per monomer molecule
Concept:

Step-growth condensation requires polyfunctional monomers (functionality \(f \ge 2\)) capable of forming chemical linkages at two or more positions.

Formula / Reaction:

$$n\,\text{A}-\text{R}-\text{A} + n\,\text{B}-\text{R}'-\text{B} \longrightarrow -[\text{R}-\text{AB}-\text{R}'-\text{AB}]_n- + (2n-1)\,\text{xy}$$

Solution:

  • Bifunctional monomers (diols, dicarboxylic acids, diamines) allow step-wise chain extension from both ends to build high-molecular-weight polymers.


Why other options are incorrect:

  • Option A: Monofunctional species terminate chain propagation prematurely.


  • Option B: Non-polar unreactive frameworks cannot undergo condensation reactions.


  • Option D: Carbon-carbon double bonds undergo chain-growth addition polymerization.

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