Chemistry Stoichiometry MDCAT 2017
PMDC Verified Question 86 of 105
A researcher has prepared a sample of 1-Bromopropane from 10g of 1-propanol. After purification he had made 12g of product. Which of the following is percentage yield? (The test was reconducted)
A
60%
B
90%
C
58.5%
D
50%
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: 58.5%
Concept:

Percentage yield measures the efficiency of a reaction by comparing the actual amount of product obtained against the theoretical maximum predicted by stoichiometry.

Formula:

$$ \% \text{ Yield} = \left( \frac{\text{Actual Yield}}{\text{Theoretical Yield}} \right) \times 100 $$

Solution:

  • Reaction: 1-propanol (\( \text{C}_3\text{H}_8\text{O} \)) \( \rightarrow \) 1-bromopropane (\( \text{C}_3\text{H}_7\text{Br} \)).


  • Molar mass of 1-propanol = 60 g/mol. Molar mass of 1-bromopropane = 123 g/mol.


  • According to stoichiometry, 60g of reactant theoretically produces 123g of product.


  • Therefore, 10g of reactant theoretically produces: \( (123 / 60) \times 10 = 20.5 \text{ g} \).


  • The Actual yield given is 12g.


  • \( \% \text{ Yield} = (12 / 20.5) \times 100 = 58.53\% \).


Why other options are incorrect:

  • 60%, 90%, 50%: These numbers are incorrect mathematical derivations and do not reflect the true ratio of 12g to 20.5g.

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