Chemistry Thermochemistry NUMS 2024
PMDC Verified Question 21 of 81
Identify standard enthalpy of reaction for the following reaction:
A
\( H_{2(g)} + 1/2 O_{2(g)} \rightarrow H_2O_{(l)} \)
B
\( S_{(g)} + 3/2 O_{2(g)} \rightarrow SO_{3(g)} \)
C
\( 2Al_{(s)} + Fe_2O_{3(s)} \rightarrow Al_2O_{3(s)} + 2Fe_{(s)} \)
D
\( CO_{(g)} + 1/2 O_{2(g)} \rightarrow CO_{2(g)} \)
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Propolis Cognitive Error Autopsy

Official Correct Choice:
Option C: \( 2Al_{(s)} + Fe_2O_{3(s)} \rightarrow Al_2O_{3(s)} + 2Fe_{(s)} \)
Concept:

This conceptual question tests the ability to distinguish between exclusive, specific thermodynamic definitions. "Enthalpy of reaction" is the broad, generalized term used when a reaction does not cleanly fit the strict definitions of formation, combustion, or atomization.

Solution:

  • Option A is the enthalpy of Formation of water (and also Combustion of hydrogen).


  • Option D is the enthalpy of Combustion of carbon monoxide.


  • Option B has sulfur in a gaseous state (\( S_{(g)} \)), which violates standard state rules (Sulfur is a solid at standard conditions), disqualifying it from standard terminology.


  • Option C is a classic thermite displacement reaction. It is neither a formation from elements, nor a standard combustion with oxygen gas. Therefore, its energy change is exclusively classified by the generalized term: standard enthalpy of reaction (\( \Delta H_{rxn} \)).


Why other options are incorrect:

As noted, options A and D hold more highly specific thermochemical names. The question seeks the equation where the broad term is its only applicable label.

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