Chemistry Chemical Bonding ETEA 2022
PMDC Verified Question 47 of 102
Which one of the following elements has the largest second ionization energy?
A
K
B
Ca
C
Cl
D
Bi
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option A: K
Concept:

The second ionization energy spikes massively when the removal of the second electron requires breaking into a highly stable, completely filled noble gas core.

Formula:

$$ \text{K}^+ \text{ configuration: } 1s^2, 2s^2, 2p^6, 3s^2, 3p^6 \text{ (Argon core)} $$

Solution:

  • Potassium (K) is a Group 1 alkali metal. It easily loses its single valence electron to form a \( \text{K}^+ \) ion.


  • This \( \text{K}^+ \) ion is isoelectronic with Argon, possessing a perfectly stable octet.


  • Removing a second electron requires disrupting this incredibly stable core, demanding a massive amount of energy compared to elements with multiple valence electrons.


Why other options are incorrect:

  • Option B, Option C, Option D: Calcium, Chlorine, and Bismuth have multiple electrons in their valence shell. Their second ionization does not involve breaking a noble gas core.

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