Chemistry Chemical Bonding DUHS 2022
PMDC Verified Question 48 of 102
The dipole moment of \( \text{CO}_2 \) is zero because it is:
A
Angular
B
Linear
C
Triatomic
D
Pyramidal
Tap any option to test your recall and reveal the step-by-step Propolis autopsy.

Propolis Cognitive Error Autopsy

Official Correct Choice:
Option B: Linear
Concept:

A molecule's net dipole moment is the vector sum of its individual bond dipoles. If the molecule is perfectly symmetrical, these vectors cancel out.

Formula:

$$ \text{O} = \text{C} = \text{O} \quad (180^{\circ}) $$

Solution:

  • Carbon dioxide (\( \text{CO}_2 \)) is an \( \text{AB}_2 \) type molecule with no lone pairs on the central Carbon atom.


  • This gives it a perfectly linear geometry.


  • The two highly electronegative Oxygen atoms pull electron density equally in exactly opposite directions, causing the bond dipole vectors to sum to zero.


Why other options are incorrect:

  • Option A & Option D: These geometries are asymmetrical and would result in a net polar molecule.
  • Option C: Being triatomic does not guarantee a zero dipole (e.g., \( \text{H}_2\text{O} \) is triatomic and highly polar).

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